Information card for entry 4080430

Structure parameters

• Formula: C19 H30 Fe Si2
• Calculated formula: C19 H30 Fe Si2
• SMILES: [FeH2]123456([Si](c8ccccc8[Si]1(C)C)(C)C)[cH]1[c]2([cH]3[c]4([cH]5[c]61C)C)C
• Title of publication: Disilametallacycles as a Platform for Stabilizing M(II) and M(IV) (M = Fe, Ru) Centers: Synthesis and Characterization of Half-Sandwich Complexes and Their Application to Catalytic Double Silylation of Alkenes and Alkynes
• Authors of publication: Sunada, Yusuke; Imaoka, Tsuyoshi; Nagashima, Hideo
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 7
• Pages of publication: 2112
• a: 11.947 ± 0.004 Å
• b: 19.428 ± 0.006 Å
• c: 16.674 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3870 ± 2 ų
• Cell temperature: 123 K
• Ambient diffraction temperature: 123 K
• Number of distinct elements: 4
• Space group number: 60
• Hermann-Mauguin space group symbol: P b c n
• Hall space group symbol: -P 2n 2ab
• Residual factor for significantly intense reflections: 0.0545
• Weighted residual factors for all reflections included in the refinement: 0.1843
• Goodness-of-fit parameter for all reflections included in the refinement: 1.006
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No