Information card for entry 4080474

Structure parameters

• Formula: C62 H114 Cl N7 O Si6 Yb2
• Calculated formula: C62 H114 Cl N7 O Si6 Yb2
• SMILES: [Yb]1(N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)[N](=C(C)C=C(N1c1cc(ccc1)N1[Yb](N([Si](C)(C)C)[Si](C)(C)C)(Cl)([O]2CCCC2)[N](=C(C=C1C)C)c1c(cccc1C(C)C)C(C)C)C)c1c(cccc1C(C)C)C(C)C
• Title of publication: Unexpected C‒H Bond Activation Promoted by Bimetallic Lanthanide Amido Complexes Bearing a META-Phenylene-Bridged Bis(β-diketiminate) Ligand
• Authors of publication: Sun, Song; Sun, Qiu; Zhao, Bei; Zhang, Yong; Shen, Qi; Yao, Yingming
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 6
• Pages of publication: 1876
• a: 11.505 ± 0.005 Å
• b: 18.382 ± 0.008 Å
• c: 19.229 ± 0.008 Å
• α: 99.74 ± 0.01°
• β: 96.401 ± 0.007°
• γ: 106.71 ± 0.009°
• Cell volume: 3783 ± 3 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1509
• Residual factor for significantly intense reflections: 0.1014
• Weighted residual factors for significantly intense reflections: 0.2296
• Weighted residual factors for all reflections included in the refinement: 0.2645
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No