Information card for entry 4080893

Structure parameters

• Chemical name: Ti(O(CH2CH2NSiMe3)(CH2CH2NC(H)C(Ph)NSiMe3)NPh2
• Formula: C31 H44 N4 O Si2 Ti
• Calculated formula: C31 H44 N4 O Si2 Ti
• SMILES: [Ti]123([O](CCN2C=C(N1[Si](C)(C)C)c1ccc(cc1)C)CCN3[Si](C)(C)C)N(c1ccccc1)c1ccccc1
• Title of publication: Synthesis and Reactivity of Titanium Hydrazido Complexes Supported by Diamido-Ether Ligands
• Authors of publication: Unruangsri, Junjuda; Morgan, Hannah; Schwarz, Andrew D.; Schofield, A. Daniel; Mountford, Philip
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 10
• Pages of publication: 3091
• a: 8.6182 ± 0.0007 Å
• b: 11.8395 ± 0.0009 Å
• c: 17.0966 ± 0.0014 Å
• α: 74.409 ± 0.007°
• β: 85.427 ± 0.006°
• γ: 74.224 ± 0.007°
• Cell volume: 1616.9 ± 0.2 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0446
• Residual factor for significantly intense reflections: 0.0394
• Weighted residual factors for all reflections: 0.0426
• Weighted residual factors for significantly intense reflections: 0.0409
• Weighted residual factors for all reflections included in the refinement: 0.0405
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0298
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No