Information card for entry 4081625

Structure parameters

• Common name: complex_6_tuckin
• Formula: C36 H62 Si2 U
• Calculated formula: C36 H62 Si2 U
• SMILES: [CH2]1=[C]23[C]4(C)=[C]5([C]6(C)=[C]2(C)[U]2789%10%11%1213456[C]1(=[CH]2[CH]7=[C]8([CH]9=[CH]%10[CH]%11=[CH]%121)[Si](C(C)C)(C(C)C)C(C)C)[Si](C(C)C)(C(C)C)C(C)C)C
• Title of publication: Synthesis and CO2Insertion Chemistry of Uranium(IV) Mixed-Sandwich Alkyl and Hydride Complexes
• Authors of publication: Higgins, Jessica A.; Cloke, F. Geoffrey N.; Roe, S. Mark
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 19
• Pages of publication: 5244
• a: 16.0245 ± 0.0002 Å
• b: 8.5072 ± 0.0001 Å
• c: 26.9278 ± 0.0003 Å
• α: 90°
• β: 103.081 ± 0.001°
• γ: 90°
• Cell volume: 3575.64 ± 0.07 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.039
• Residual factor for significantly intense reflections: 0.0285
• Weighted residual factors for significantly intense reflections: 0.085
• Weighted residual factors for all reflections included in the refinement: 0.0959
• Goodness-of-fit parameter for all reflections included in the refinement: 0.714
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No