Information card for entry 4082433

Structure parameters

• Formula: C28 H11 O16 Os3 Sb W
• Calculated formula: C28 H11 O16 Os3 Sb W
• SMILES: [Os]12([Os]([H]1)([Os]2(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O])([Sb]([W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O]
• Title of publication: Oxidative Addition across Sb‒H and Sb‒Sb Bonds by an Osmium Carbonyl Cluster: Trapping the Intermediate
• Authors of publication: Li, Ying-Zhou; Ganguly, Rakesh; Leong, Weng Kee
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 3
• Pages of publication: 823
• a: 11.2374 ± 0.0003 Å
• b: 11.8935 ± 0.0003 Å
• c: 12.6269 ± 0.0003 Å
• α: 82.505 ± 0.001°
• β: 85.629 ± 0.001°
• γ: 82.025 ± 0.001°
• Cell volume: 1654.1 ± 0.07 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0233
• Residual factor for significantly intense reflections: 0.0198
• Weighted residual factors for significantly intense reflections: 0.0446
• Weighted residual factors for all reflections included in the refinement: 0.0457
• Goodness-of-fit parameter for all reflections included in the refinement: 1.093
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No