Information card for entry 4083779

Structure parameters

• Formula: C28 H33 F3 N4 O8 S Si W
• Calculated formula: C28 H33 F3 N4 O8 S Si W
• SMILES: [Si]1([W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])([N](C(C)(C)C)=C(c2ccccc2)N1C(C)(C)C)[n]1ccc(cc1)N(C)C.C(F)(F)(F)S(=O)(=O)[O-]
• Title of publication: A Base-Stabilized Silyliumylidene Cation as a Ligand for Rhodium and Tungsten Complexes
• Authors of publication: Yeong, Hui-Xian; Li, Yongxin; So, Cheuk-Wai
• Journal of publication: Organometallics
• Year of publication: 2014
• Pages of publication: 140627113050000
• a: 12.6859 ± 0.0007 Å
• b: 20.4319 ± 0.0012 Å
• c: 13.4535 ± 0.0007 Å
• α: 90°
• β: 94.956 ± 0.002°
• γ: 90°
• Cell volume: 3474.1 ± 0.3 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0629
• Residual factor for significantly intense reflections: 0.0367
• Weighted residual factors for significantly intense reflections: 0.0836
• Weighted residual factors for all reflections included in the refinement: 0.1168
• Goodness-of-fit parameter for all reflections included in the refinement: 1.096
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No