Information card for entry 4084340

Structure parameters

• Common name: tep2aupcl
• Formula: C55 H45 Au Cl3 P3 Te
• Calculated formula: C55 H45 Au Cl3 P3 Te
• SMILES: [Au]12([Te](Cl)(c3ccccc3[P]1(c1ccccc1)c1ccccc1)c1ccccc1[P]2(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1.ClCCl
• Title of publication: Telluroether to Telluroxide Conversion in the Coordination Sphere of a Metal: Oxidation-Induced Umpolung of a Te‒Au Bond
• Authors of publication: Yang, Haifeng; Lin, Tzu-Pin; Gabba\?ï, François P.
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 17
• Pages of publication: 4368
• a: 11.071 ± 0.007 Å
• b: 14.325 ± 0.008 Å
• c: 16.138 ± 0.009 Å
• α: 84.254 ± 0.007°
• β: 85.54 ± 0.006°
• γ: 71.043 ± 0.006°
• Cell volume: 2406 ± 2 ų
• Cell temperature: 110 ± 2 K
• Ambient diffraction temperature: 110 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1156
• Residual factor for significantly intense reflections: 0.0685
• Weighted residual factors for significantly intense reflections: 0.1637
• Weighted residual factors for all reflections included in the refinement: 0.1897
• Goodness-of-fit parameter for all reflections included in the refinement: 1.005
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No