Information card for entry 4084965

Structure parameters

• Formula: C37 H53 Ir O Ru2 Si
• Calculated formula: C37 H28.5 Ir0.999 O Ru1.999 Si
• Title of publication: Trinuclear μ3-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a μ3-Silyl Complex of Ru2Ir into μ-Silyl and μ3-Silylene Complexes
• Authors of publication: Nagaoka, Masahiro; Shima, Takanori; Takao, Toshiro; Suzuki, Hiroharu
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 24
• Pages of publication: 7232
• a: 11.2222 ± 0.0004 Å
• b: 18.454 ± 0.0007 Å
• c: 19.4333 ± 0.0006 Å
• α: 109.298 ± 0.0012°
• β: 98.055 ± 0.001°
• γ: 104.264 ± 0.0012°
• Cell volume: 3571.7 ± 0.2 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0798
• Residual factor for significantly intense reflections: 0.0525
• Weighted residual factors for significantly intense reflections: 0.1254
• Weighted residual factors for all reflections included in the refinement: 0.1433
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No