Information card for entry 4085243

Structure parameters

• Formula: C36 H96 Li6 N6 Si6
• Calculated formula: C36 H96 Li6 N6 Si6
• SMILES: [Si]([NH]12[Li]3[NH]4([Si](C)(C)C(C)(C)C)[Li]5[NH]3([Si](C)(C)C(C)(C)C)[Li]1[NH]1([Si](C)(C)C(C)(C)C)[Li]3[NH]5([Si](C)(C)C(C)(C)C)[Li]4[NH]3([Si](C)(C)C(C)(C)C)[Li]21)(C)(C)C(C)(C)C
• Title of publication: Homoleptic Trigonal Planar Lanthanide Complexes Stabilized by Superbulky Silylamide Ligands
• Authors of publication: Goodwin, Conrad A. P.; Joslin, Kristian C.; Lockyer, Selena J.; Formanuik, Alasdair; Morris, Gareth A.; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo. J.; Mills, David P.
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2314
• a: 12.3694 ± 0.0011 Å
• b: 19.5146 ± 0.001 Å
• c: 13.2445 ± 0.0011 Å
• α: 90°
• β: 117.52 ± 0.011°
• γ: 90°
• Cell volume: 2835.3 ± 0.5 ų
• Cell temperature: 100.3 ± 0.5 K
• Ambient diffraction temperature: 100.3 ± 0.5 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0649
• Residual factor for significantly intense reflections: 0.0479
• Weighted residual factors for significantly intense reflections: 0.1172
• Weighted residual factors for all reflections included in the refinement: 0.1308
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No