Information card for entry 4085254

Structure parameters

• Chemical name: tris(bis(tertbutyldimethylsilyl))amido lanthanum
• Formula: C36 H90 La N3 Si6
• Calculated formula: C36 H90 La N3 Si6
• SMILES: C(C)([Si](C)(C)N([La](N([Si](C(C)(C)C)(C)C)[Si](C(C)(C)C)(C)C)N([Si](C(C)(C)C)(C)C)[Si](C(C)(C)C)(C)C)[Si](C(C)(C)C)(C)C)(C)C
• Title of publication: Homoleptic Trigonal Planar Lanthanide Complexes Stabilized by Superbulky Silylamide Ligands
• Authors of publication: Goodwin, Conrad A. P.; Joslin, Kristian C.; Lockyer, Selena J.; Formanuik, Alasdair; Morris, Gareth A.; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo. J.; Mills, David P.
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2314
• a: 21.8384 ± 0.0009 Å
• b: 13.2402 ± 0.0005 Å
• c: 17.854 ± 0.0008 Å
• α: 90°
• β: 110.967 ± 0.005°
• γ: 90°
• Cell volume: 4820.6 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 1 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.053
• Residual factor for significantly intense reflections: 0.0395
• Weighted residual factors for significantly intense reflections: 0.0844
• Weighted residual factors for all reflections included in the refinement: 0.0915
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No