Thermal Isomerization of the Buchwald Seven-Membered Zirconacyclocumulene and Its Interaction with Acetylenes. Synthesis and Structures of Novel Seven-Membered Zirconacyclocumulene Complexes
Authors of publication
Burlakov, Vladimir V.; Bogdanov, Vyacheslav S.; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Lyssenko, Konstantin A.; Ananyev, Ivan V.; Rosenthal, Uwe; Shur, Vladimir B.
Journal of publication
Organometallics
Year of publication
2015
Journal volume
34
Journal issue
11
Pages of publication
2471
a
6.5912 ± 0.0002 Å
b
13.0722 ± 0.0004 Å
c
15.5139 ± 0.0004 Å
α
90.062 ± 0.002°
β
94.187 ± 0.002°
γ
96.88 ± 0.002°
Cell volume
1323.47 ± 0.07 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
3
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0533
Residual factor for significantly intense reflections
0.0383
Weighted residual factors for significantly intense reflections
0.095
Weighted residual factors for all reflections included in the refinement
0.1066
Goodness-of-fit parameter for all reflections included in the refinement
