Information card for entry 4085747

Structure parameters

• Formula: C23 H29 Co I N P2
• Calculated formula: C23 H29 Co I N P2
• SMILES: [Co]12(I)([N](=Cc3c1cccc3)c1cccc3cccc2c13)([P](C)(C)C)[P](C)(C)C
• Title of publication: Synthesis and Reactivity of a Hydrido CNC Pincer Cobalt(III) Complex and Its Application in Hydrosilylation of Aldehydes and Ketones
• Authors of publication: Zhou, Hongwei; Sun, Hongjian; Zhang, Shumiao; Li, Xiaoyan
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 1479
• a: 22.537 ± 0.003 Å
• b: 22.537 ± 0.003 Å
• c: 8.829 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 3883.6 ± 1.1 ų
• Cell temperature: 273 ± 2 K
• Ambient diffraction temperature: 273 ± 2 K
• Number of distinct elements: 6
• Space group number: 147
• Hermann-Mauguin space group symbol: P -3
• Hall space group symbol: -P 3
• Residual factor for all reflections: 0.1114
• Residual factor for significantly intense reflections: 0.0439
• Weighted residual factors for significantly intense reflections: 0.0991
• Weighted residual factors for all reflections included in the refinement: 0.1147
• Goodness-of-fit parameter for all reflections included in the refinement: 0.861
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No