Information card for entry 4086363

Structure parameters

• Formula: C31 H59 Cl6 N O Os P2
• Calculated formula: C31 H59 Cl6 N O Os P2
• SMILES: [OsH](Cl)(Cl)([P](C(C)C)(C(C)C)C(C)C)([P](C(C)C)(C(C)C)C(C)C)#CCCCC(=O)Nc1ccccc1.ClCCl.ClCCl
• Title of publication: Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes.
• Authors of publication: Casanova, Noelia; Esteruelas, Miguel A.; Gulías, Moisés; Larramona, Carmen; Mascareñas, José L; Oñate, Enrique
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 2
• Pages of publication: 91 - 99
• a: 8.849 ± 0.002 Å
• b: 12.11 ± 0.003 Å
• c: 19.188 ± 0.005 Å
• α: 93.888 ± 0.004°
• β: 92.002 ± 0.004°
• γ: 105.872 ± 0.004°
• Cell volume: 1970.2 ± 0.8 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0581
• Residual factor for significantly intense reflections: 0.0395
• Weighted residual factors for significantly intense reflections: 0.0689
• Weighted residual factors for all reflections included in the refinement: 0.0754
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No