Information card for entry 4086669

Structure parameters

• Formula: C33 H59 N O Si2 Ti2
• Calculated formula: C33 H59 N O Si2 Ti2
• Title of publication: C‒H Activation on an Oxo-Bridged Dititanium Complex: From Alkyl to μ-Alkylidene Functionalities
• Authors of publication: González-Pérez, Juan I.; Martín, Avelino; Mena, Miguel; Santamaría, Cristina
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 15
• Pages of publication: 2488
• a: 16.1779 ± 0.0016 Å
• b: 9.2899 ± 0.0006 Å
• c: 23.711 ± 0.003 Å
• α: 90°
• β: 92.67 ± 0.008°
• γ: 90°
• Cell volume: 3559.7 ± 0.6 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1071
• Residual factor for significantly intense reflections: 0.0636
• Weighted residual factors for significantly intense reflections: 0.142
• Weighted residual factors for all reflections included in the refinement: 0.1701
• Goodness-of-fit parameter for all reflections included in the refinement: 1.068
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No