Transition-Metal-Free Formation of C-E Bonds (E = C, N, O, S) and Formation of C-M Bonds (M = Mn, Mo) from N-Heterocyclic Carbene Mediated Fluoroalkene C-F Bond Activation.
Authors of publication
Leclerc, Matthew C.; Gabidullin, Bulat M.; Da Gama, Jason G.; Daifuku, Stephanie L.; Iannuzzi, Theresa E.; Neidig, Michael L.; Baker, R. Tom
Journal of publication
Organometallics
Year of publication
2017
Journal volume
36
Journal issue
4
Pages of publication
849 - 857
a
8.2473 ± 0.0009 Å
b
14.5433 ± 0.0015 Å
c
28.32 ± 0.003 Å
α
90°
β
90.445 ± 0.005°
γ
90°
Cell volume
3396.7 ± 0.6 Å3
Cell temperature
200 ± 2 K
Ambient diffraction temperature
200 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.1499
Residual factor for significantly intense reflections
0.1102
Weighted residual factors for significantly intense reflections
0.3035
Weighted residual factors for all reflections included in the refinement
0.3305
Goodness-of-fit parameter for all reflections included in the refinement
