Diverging Pathways in the Activation of Allenes with Lewis Acids and Bases: Addition, 1,2-Carboboration, and Cyclization
Authors of publication
Melen, Rebecca L.; Wilkins, Lewis C.; Kariuki, Benson M.; Wadepohl, Hubert; Gade, Lutz H.; Hashmi, A. Stephen K.; Stephan, Douglas W.; Hansmann, Max M.
Journal of publication
Organometallics
Year of publication
2015
Journal volume
34
Journal issue
16
Pages of publication
4127
a
11.3113 ± 0.0004 Å
b
11.5408 ± 0.0005 Å
c
12.6612 ± 0.0005 Å
α
105.469 ± 0.004°
β
96.466 ± 0.003°
γ
91.745 ± 0.003°
Cell volume
1579.64 ± 0.11 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
5
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0765
Residual factor for significantly intense reflections
0.0499
Weighted residual factors for significantly intense reflections
0.1199
Weighted residual factors for all reflections included in the refinement
0.1388
Goodness-of-fit parameter for all reflections included in the refinement
