Information card for entry 4088505

Structure parameters

• Formula: C21 H30 F6 N2 Rh Sb
• Calculated formula: C21 H30 F6 N2 Rh Sb
• SMILES: [Sb](F)(F)(F)(F)(F)[F-].[Rh]12345([NH2]C(c6c5cccc6)(C)C)([N]#CC)[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: Cationic Iridium and Rhodium Complexes with C‒N Chelating Primary Benzylic Amine Ligands as Potent Catalysts for Hydrogenation of Unsaturated Carbon‒Nitrogen Bonds
• Authors of publication: Sato, Yasuhiro; Kayaki, Yoshihito; Ikariya, Takao
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 9
• Pages of publication: 1257
• a: 8.502 ± 0.005 Å
• b: 11.007 ± 0.006 Å
• c: 13.633 ± 0.007 Å
• α: 96.292 ± 0.006°
• β: 93.694 ± 0.008°
• γ: 106.951 ± 0.006°
• Cell volume: 1206.8 ± 1.2 ų
• Cell temperature: 123 K
• Ambient diffraction temperature: 123 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0401
• Weighted residual factors for all reflections included in the refinement: 0.1148
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No