Information card for entry 4101285

Structure parameters

• Chemical name: dichlorobis(1,6-bisdiphenylphosphinohexane)cobalt
• Formula: C69 H82 Cl4 Co2 O3 P4
• Calculated formula: C69 H82 Cl4 Co2 O3 P4
• Title of publication: Cobalt-catalyzed trimethylsilylmethylmagnesium-promoted radical alkenylation of alkyl halides: a complement to the Heck reaction.
• Authors of publication: Affo, Walter; Ohmiya, Hirohisa; Fujioka, Takuma; Ikeda, Yousuke; Nakamura, Tomoaki; Yorimitsu, Hideki; Oshima, Koichiro; Imamura, Yuki; Mizuta, Tsutomu; Miyoshi, Katsuhiko
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2006
• Journal volume: 128
• Journal issue: 24
• Pages of publication: 8068 - 8077
• a: 15.38 ± 0.0002 Å
• b: 15.404 ± 0.0002 Å
• c: 18.353 ± 0.0004 Å
• α: 75.291 ± 0.001°
• β: 66.291 ± 0.001°
• γ: 65.176 ± 0.001°
• Cell volume: 3594.25 ± 0.1 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0824
• Residual factor for significantly intense reflections: 0.0567
• Weighted residual factors for significantly intense reflections: 0.1448
• Weighted residual factors for all reflections included in the refinement: 0.1617
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No