Information card for entry 4103074

Structure parameters

• Formula: C56.33 H52.65 Cl0.65 F4 N O Rh Si
• Calculated formula: C56.325 H52.65 Cl0.65 F4 N O Rh Si
• Title of publication: Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes
• Authors of publication: Takahiro Nishimura; Hiroki Makino; Makoto Nagaosa; Tamio Hayashi
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2010
• Journal volume: 132
• Pages of publication: 12865 - 12867
• a: 11.81 ± 0.002 Å
• b: 14.161 ± 0.003 Å
• c: 28.699 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4799.7 ± 1.5 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 8
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0463
• Residual factor for significantly intense reflections: 0.0407
• Weighted residual factors for significantly intense reflections: 0.0895
• Weighted residual factors for all reflections included in the refinement: 0.0927
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No