Information card for entry 4103589

Structure parameters

• Formula: C27 H35 F6 P Rh Sb
• Calculated formula: C27 H35 F6 P Rh Sb
• SMILES: [Rh]1234567([P]([C]87=[C]6(C5)C=CC=C8C)(C)c5c(cccc5C)C)[c]5([c]4([c]3([c]2([c]15C)C)C)C)C.[Sb](F)(F)(F)(F)(F)[F-]
• Title of publication: A Cationic Rh(III) Complex That Efficiently Catalyzes Hydrogen Isotope Exchange in Hydrosilanes
• Authors of publication: Jesús Campos; Ana C. Esqueda; Joaquín López-Serrano; Luis Sánchez; Fernando P. Cossio; Abel de Cozar; Eleuterio Álvarez; Celia Maya; Ernesto Carmona
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2010
• Journal volume: 132
• Pages of publication: 16765 - 16767
• a: 25.6591 ± 0.0013 Å
• b: 7.8808 ± 0.0004 Å
• c: 13.9773 ± 0.0008 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2826.4 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 29
• Hermann-Mauguin space group symbol: P c a 21
• Hall space group symbol: P 2c -2ac
• Residual factor for all reflections: 0.0606
• Residual factor for significantly intense reflections: 0.0333
• Weighted residual factors for significantly intense reflections: 0.0608
• Weighted residual factors for all reflections included in the refinement: 0.07
• Goodness-of-fit parameter for all reflections included in the refinement: 1.055
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No