Information card for entry 4104458

Structure parameters

• Common name: HLSi(OTf)-Ni(CO)3*1/2hexane
• Formula: C36 H48 F3 N2 Ni O6 S Si
• Calculated formula: C36 H48 F3 N2 Ni O6 S Si
• Title of publication: Diketiminate Silicon(II) and Related NHSi Ligands Generated in the Coordination Sphere of Nickel(0)
• Authors of publication: Antje Meltzer; Carsten Präsang; Matthias Driess
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 7232 - 7233
• a: 10.8132 ± 0.0003 Å
• b: 11.6057 ± 0.0003 Å
• c: 17.4222 ± 0.0005 Å
• α: 105.188 ± 0.003°
• β: 98.328 ± 0.002°
• γ: 107.146 ± 0.003°
• Cell volume: 1956.91 ± 0.11 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0523
• Residual factor for significantly intense reflections: 0.0364
• Weighted residual factors for significantly intense reflections: 0.0791
• Weighted residual factors for all reflections included in the refinement: 0.0836
• Goodness-of-fit parameter for all reflections included in the refinement: 1.016
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No