Information card for entry 4104788

Structure parameters

• Formula: C30 H76 N8 Si6 U2
• Calculated formula: C30 H76 N8 Si6 U2
• SMILES: [U]12345N6[Si]([CH2]1[U]178(C[Si](N2CC[N]4(CC6)CCN3[Si](C)(C)C)(C)C)N([Si](C)(C)C)CC[N]8(CC[N]51[Si](C)(C)C)CCN7[Si](C)(C)C)(C)C
• Title of publication: A Crystallizable Dinuclear Tuck-In-Tuck-Over Tuck-Over Dialkyl Tren Uranium Complex and Double Dearylation of BPh4- To Give the BPh2-Functionalized Metallocycle [U{N(CH2CH2NSiMe3)2(CH2CH2NSiMe2CHBPh2)}(THF)]
• Authors of publication: Benedict M. Gardner; Jonathan McMaster; William Lewis; Alexander J. Blake; Stephen T. Liddle
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 10388 - 10389
• a: 10.9142 ± 0.0015 Å
• b: 16.979 ± 0.002 Å
• c: 25.765 ± 0.004 Å
• α: 90°
• β: 100.067 ± 0.003°
• γ: 90°
• Cell volume: 4701.1 ± 1.1 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0481
• Residual factor for significantly intense reflections: 0.0282
• Weighted residual factors for significantly intense reflections: 0.0563
• Weighted residual factors for all reflections included in the refinement: 0.0616
• Goodness-of-fit parameter for all reflections included in the refinement: 1.016
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No