Information card for entry 4105094

Structure parameters

• Common name: (dmpm)Mn(py)2
• Chemical name: bis-pyridine (1,9-dimesityl-5,5-dimethyldipyrromethanato)manganese(II)
• Formula: C77.61 H85.19 Mn2 N7.61 O0.4
• Calculated formula: C77.605 H85.185 Mn2 N7.605 O0.395
• Title of publication: Unusual Electronic Structure of First Row Transition Metal Complexes Featuring Redox-Active Dipyrromethane Ligands
• Authors of publication: Evan R. King; Theodore A. Betley
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 14374 - 14380
• a: 12.0232 ± 0.0002 Å
• b: 15.6642 ± 0.0003 Å
• c: 18.963 ± 0.0003 Å
• α: 70.65 ± 0.001°
• β: 87.145 ± 0.001°
• γ: 83.73 ± 0.001°
• Cell volume: 3349.13 ± 0.1 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.095
• Residual factor for significantly intense reflections: 0.0484
• Weighted residual factors for significantly intense reflections: 0.0994
• Weighted residual factors for all reflections included in the refinement: 0.117
• Goodness-of-fit parameter for all reflections included in the refinement: 0.998
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No