Information card for entry 4105414

Structure parameters

• Formula: C14 H34 Li N3 Si
• Calculated formula: C14 H34 Li N3 Si
• SMILES: C[Si]1(C)C(CC)[Li]23[N](C1)(C)CC[N]2(C)CC[N]3(C)C
• Title of publication: Low-Temperature Addition of Organolithiums to Functionalized Vinylsilanes under Formation of Secondary α-Lithiated Alkylsilanes
• Authors of publication: Christian Unkelbach; Carsten Strohmann
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 17044 - 17045
• a: 8.803 ± 0.005 Å
• b: 9.319 ± 0.004 Å
• c: 12.224 ± 0.004 Å
• α: 82.89 ± 0.04°
• β: 86.29 ± 0.05°
• γ: 71.87 ± 0.06°
• Cell volume: 945.3 ± 0.8 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0808
• Residual factor for significantly intense reflections: 0.0639
• Weighted residual factors for significantly intense reflections: 0.1867
• Weighted residual factors for all reflections included in the refinement: 0.1983
• Goodness-of-fit parameter for all reflections included in the refinement: 1.089
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No