Information card for entry 4105823

Structure parameters

• Chemical name: bis(mu-phenylamido)bis(tetrahydrofuran) bis[bis(trimethylsilyl)amido]dimanganese(II)
• Formula: C32 H64 Mn2 N4 O2 Si4
• Calculated formula: C32 H64 Mn2 N4 O2 Si4
• SMILES: C[Si](C)(C)N([Mn]1([NH](c2ccccc2)[Mn](N([Si](C)(C)C)[Si](C)(C)C)([NH]1c1ccccc1)[O]1CCCC1)[O]1CCCC1)[Si](C)(C)C
• Title of publication: Synthesis of Tetranuclear, Four-Coordinate Manganese Clusters with "Pinned Butterfly" Geometry Formed by Metal-Mediated N-N Bond Cleavage in Diphenylhydrazine
• Authors of publication: Clifton R. Hamilton; Regina A. Baglia; Alexander D. Gordon; Michael J. Zdilla
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2011
• Journal volume: 133
• Pages of publication: 4208 - 4211
• a: 8.817 ± 0.004 Å
• b: 21.151 ± 0.009 Å
• c: 10.788 ± 0.004 Å
• α: 90°
• β: 95.286 ± 0.007°
• γ: 90°
• Cell volume: 2003.3 ± 1.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0294
• Residual factor for significantly intense reflections: 0.024
• Weighted residual factors for significantly intense reflections: 0.0614
• Weighted residual factors for all reflections included in the refinement: 0.0644
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No