Information card for entry 4105826

Structure parameters

• Common name: manganese bis(tms-amide) bis(THF)
• Chemical name: bis(tetrahydrofuran)bis[bis(trimethylsilylamido)]manganese(II)
• Formula: C20 H52 Mn N2 O2 Si4
• Calculated formula: C20 H52 Mn N2 O2 Si4
• SMILES: [Mn](N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)([O]1CCCC1)[O]1CCCC1
• Title of publication: Synthesis of Tetranuclear, Four-Coordinate Manganese Clusters with "Pinned Butterfly" Geometry Formed by Metal-Mediated N-N Bond Cleavage in Diphenylhydrazine
• Authors of publication: Clifton R. Hamilton; Regina A. Baglia; Alexander D. Gordon; Michael J. Zdilla
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2011
• Journal volume: 133
• Pages of publication: 4208 - 4211
• a: 13.8679 ± 0.0019 Å
• b: 12.1188 ± 0.0016 Å
• c: 18.512 ± 0.003 Å
• α: 90°
• β: 97.116 ± 0.002°
• γ: 90°
• Cell volume: 3087.2 ± 0.8 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0458
• Residual factor for significantly intense reflections: 0.0333
• Weighted residual factors for significantly intense reflections: 0.0926
• Weighted residual factors for all reflections included in the refinement: 0.097
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No