Information card for entry 4106579

Structure parameters

• Common name: [L(tBu)CoF]2
• Formula: C70 H106 Co2 F2 N4
• Calculated formula: C70 H106 Co2 F2 N4
• Title of publication: A Masked Two-Coordinate Cobalt(I) Complex That Activates C-F Bonds
• Authors of publication: Thomas R. Dugan; Xianru Sun; Elena V. Rybak-Akimova; Olayinka Olatunji-Ojo; Thomas R. Cundari; Patrick L. Holland
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2011
• Journal volume: 133
• Pages of publication: 12418 - 12421
• a: 24.218 ± 0.002 Å
• b: 12.1814 ± 0.0012 Å
• c: 26.222 ± 0.003 Å
• α: 90°
• β: 111.373 ± 0.002°
• γ: 90°
• Cell volume: 7203.7 ± 1.2 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0973
• Residual factor for significantly intense reflections: 0.0541
• Weighted residual factors for significantly intense reflections: 0.1334
• Weighted residual factors for all reflections included in the refinement: 0.1494
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No