Information card for entry 4107143

Structure parameters

• Formula: C110 H136 Ge6 P6 Pd6 S2
• Calculated formula: C110 H136 Ge6 P6 Pd6 S2
• SMILES: c1(ccccc1)[Ge]1(c2ccccc2)[Pd]2([P](C)(C)CC[P]2(C)C)[PdH]231[Ge]1([S](c4ccc(cc4)C(C)(C)C)[Pd]31([P](C)(C)CC[P](C)(C)[Pd]134[S](c5ccc(cc5)C(C)(C)C)[Ge]1(c1ccccc1)(c1ccccc1)[PdH]14([Ge](c4ccccc4)(c4ccccc4)[Pd]41[P](C)(C)CC[P]4(C)C)[Ge]3(c1ccccc1)c1ccccc1)[Ge]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Tetrapalladium Complex with Bridging Germylene Ligands. Structural Change of the Planar Pd4Ge3 Core
• Authors of publication: Makoto Tanabe; Naoko Ishikawa; Mai Chiba; Tomohito Ide; Kohtaro Osakada; Tomoaki Tanase
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2011
• Journal volume: 133
• Pages of publication: 18598 - 18601
• a: 13.83 ± 0.007 Å
• b: 14.631 ± 0.008 Å
• c: 16.86 ± 0.008 Å
• α: 98.179 ± 0.009°
• β: 99.519 ± 0.007°
• γ: 102.421 ± 0.008°
• Cell volume: 3229 ± 3 ų
• Cell temperature: 163 K
• Ambient diffraction temperature: 163 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.108
• Residual factor for significantly intense reflections: 0.0789
• Weighted residual factors for significantly intense reflections: 0.2363
• Weighted residual factors for all reflections included in the refinement: 0.2672
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No