Information card for entry 4108078

Structure parameters

• Common name: [Mes*NPW(CO)5]P3Nb(N[Np]Ar)3 (Et2O)
• Formula: C65.11 H96.77 N4 Nb O5.78 P4 W
• Calculated formula: C65.1076 H96.769 N4 Nb O5.7769 P4 W
• Title of publication: P2Addition to Terminal Phosphide M\τbP Triple Bonds: A Rational Synthesis of cyclo-P3 Complexes
• Authors of publication: Nicholas A. Piro; Christopher C. Cummins
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2008
• Journal volume: 130
• Pages of publication: 9524 - 9535
• a: 12.553 ± 0.002 Å
• b: 16.226 ± 0.003 Å
• c: 19.007 ± 0.004 Å
• α: 67.754 ± 0.003°
• β: 84.259 ± 0.003°
• γ: 87.128 ± 0.004°
• Cell volume: 3565 ± 1.2 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0478
• Residual factor for significantly intense reflections: 0.0339
• Weighted residual factors for significantly intense reflections: 0.0727
• Weighted residual factors for all reflections included in the refinement: 0.0786
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No