Information card for entry 4110374

Structure parameters

• Formula: C34 H61 Os P Si
• Calculated formula: C34 H61 Os P Si
• SMILES: [OsH]1234([P](C(C)C)(C(C)C)C(C)C)(=[SiH]c5c(C(C)C)cc(cc5C(C)C)C(C)C)[c]5([c]2([c]1([c]3([c]45C)C)C)C)C
• Title of publication: Hydrogen-Substituted Osmium Silylene Complexes: Effect of Charge Localization on Catalytic Hydrosilation
• Authors of publication: Paul G. Hayes; Chad Beddie; Michael B. Hall; Rory Waterman; T. Don Tilley
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2006
• Journal volume: 128
• Pages of publication: 428 - 429
• a: 35.326 ± 0.003 Å
• b: 9.2322 ± 0.0008 Å
• c: 24.865 ± 0.002 Å
• α: 90°
• β: 120.737 ± 0.001°
• γ: 90°
• Cell volume: 6970.2 ± 1 ų
• Cell temperature: 135 ± 2 K
• Ambient diffraction temperature: 135 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0586
• Residual factor for significantly intense reflections: 0.0314
• Weighted residual factors for significantly intense reflections: 0.06
• Weighted residual factors for all reflections included in the refinement: 0.0643
• Goodness-of-fit parameter for all reflections included in the refinement: 0.88
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No