Information card for entry 4110446

Structure parameters

• Chemical name: [bis(mu2-trifluoroacetateo-O,O')-bis(mu2-pivolate-O,O')-(bismuth-rhodium)]- [tris(mu2-trifluoroacetateo-O,O')-(mu2-pivolate-O,O')-(bismuth-rhodium)]
• Formula: C25 H27 Bi2 F15 O16 Rh2
• Calculated formula: C25 H27 Bi2 F15 O16 Rh2
• Title of publication: Tuning the Properties at Heterobimetallic Core: Mixed-Ligand Bismuth-Rhodium Paddlewheel Carboxylates
• Authors of publication: Evgeny V. Dikarev; Bo Li; Haitao Zhang
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2006
• Journal volume: 128
• Pages of publication: 2814 - 2815
• a: 20.9073 ± 0.0011 Å
• b: 9.6475 ± 0.0005 Å
• c: 21.6942 ± 0.0011 Å
• α: 90°
• β: 102.675 ± 0.001°
• γ: 90°
• Cell volume: 4269.2 ± 0.4 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0441
• Residual factor for significantly intense reflections: 0.0322
• Weighted residual factors for significantly intense reflections: 0.0743
• Weighted residual factors for all reflections included in the refinement: 0.0787
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No