Information card for entry 4111019

Structure parameters

• Formula: C34 H43 O4 Os P Pt Sn
• Calculated formula: C34 H43 O4 Os P Pt Sn
• SMILES: [Pt]12([Os]([Sn](c3ccccc3)(c3ccccc3)c3ccccc3)(C1=O)(C#[O])(C#[O])(C#[O])[H]2)[P](C(C)(C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Platinum Promoted Insertion of an Alkyne into a Metal-Hydrogen Bond
• Authors of publication: Richard D. Adams; Burjor Captain; Lei Zhu
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2006
• Journal volume: 128
• Pages of publication: 13672 - 13673
• a: 15.3785 ± 0.0008 Å
• b: 12.0732 ± 0.0006 Å
• c: 20.6568 ± 0.001 Å
• α: 90°
• β: 108.841 ± 0.001°
• γ: 90°
• Cell volume: 3629.8 ± 0.3 ų
• Cell temperature: 294 ± 2 K
• Ambient diffraction temperature: 294 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0539
• Residual factor for significantly intense reflections: 0.0376
• Weighted residual factors for significantly intense reflections: 0.0961
• Weighted residual factors for all reflections included in the refinement: 0.1087
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No