Information card for entry 4111309

Structure parameters

• Formula: C32 H46 O7 Si
• Calculated formula: C32 H46 O7 Si
• SMILES: [Si](OC1=C[C@@H](c2ccccc2)[C@@H](C(OC)OC)C=C2[C@H]1C(C=C2)(C(=O)OC)C(=O)OC)(C(C)C)(C(C)C)C(C)C.[Si](OC1=C[C@H](c2ccccc2)[C@H](C(OC)OC)C=C2[C@@H]1C(C=C2)(C(=O)OC)C(=O)OC)(C(C)C)(C(C)C)C(C)C
• Title of publication: W(CO)5(L)-Catalyzed Tandem Intramolecular Cyclopropanation/Cope Rearrangement for the Stereoselective Construction of Bicyclo[5.3.0]decane Framework
• Authors of publication: Hiroyuki Kusama; Yuji Onizawa; Nobuharu Iwasawa
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2006
• Journal volume: 128
• Pages of publication: 16500 - 16501
• a: 10.357 ± 0.001 Å
• b: 11.475 ± 0.0016 Å
• c: 14.484 ± 0.002 Å
• α: 74.02 ± 0.007°
• β: 88.427 ± 0.005°
• γ: 71.392 ± 0.005°
• Cell volume: 1564.9 ± 0.4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0402
• Residual factor for significantly intense reflections: 0.0361
• Weighted residual factors for significantly intense reflections: 0.0961
• Weighted residual factors for all reflections included in the refinement: 0.1007
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No