Information card for entry 4113861

Structure parameters

• Formula: C15 H47 P3 Ru Si2
• Calculated formula: C15 H46 P4 Ru Si
• SMILES: [RuH]([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[Si](C)(C)C
• Title of publication: Synthesis and Reactivity of Silyl Ruthenium Complexes: The Importance of Trans Effects in C-H Activation, Si-C Bond Formation, and Dehydrogenative Coupling of Silanes
• Authors of publication: Vladimir K. Dioumaev; Leo J. Procopio; Patrick J. Carroll; Donald H. Berry
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 8043 - 8058
• a: 15.5859 ± 0.0002 Å
• b: 10.8807 ± 0.0001 Å
• c: 29.6653 ± 0.0004 Å
• α: 90°
• β: 103.26 ± 0.004°
• γ: 90°
• Cell volume: 4896.68 ± 0.13 ų
• Cell temperature: 210 ± 2 K
• Ambient diffraction temperature: 210 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0444
• Residual factor for significantly intense reflections: 0.0391
• Weighted residual factors for all reflections: 0.1024
• Weighted residual factors for significantly intense reflections: 0.0984
• Goodness-of-fit parameter for all reflections: 1.125
• Goodness-of-fit parameter for significantly intense reflections: 1.135
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No