Information card for entry 4113916

Structure parameters

• Common name: [((Ph2SiP2)Pt)2(biphenyl)][B(C6F5)4]24oxylene
• Formula: C168 H118 B2 F40 P4 Pt2 Si2
• Calculated formula: C163.2 H112 B2 F40 P4 Pt2 Si2
• Title of publication: Zwitterionic and Cationic Bis(phosphine) Platinum(II) Complexes: Structural, Electronic, and Mechanistic Comparisons Relevant to Ligand Exchange and Benzene C-H Activation Processes
• Authors of publication: J. Christopher Thomas; Jonas C. Peters
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 8870 - 8888
• a: 15.3609 ± 0.0008 Å
• b: 17.3619 ± 0.0009 Å
• c: 32.5391 ± 0.0017 Å
• α: 93.281 ± 0.001°
• β: 95.378 ± 0.001°
• γ: 105.286 ± 0.001°
• Cell volume: 8303.7 ± 0.8 ų
• Cell temperature: 98 ± 2 K
• Ambient diffraction temperature: 98 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1675
• Residual factor for significantly intense reflections: 0.1267
• Weighted residual factors for significantly intense reflections: 0.2483
• Weighted residual factors for all reflections included in the refinement: 0.2521
• Goodness-of-fit parameter for all reflections included in the refinement: 4.558
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No