Information card for entry 4113998

Structure parameters

• Formula: C45 H32 B F15 Hf Si
• Calculated formula: C49 H32 B F15 Hf Si
• Title of publication: Cationic Hafnium Silyl Complexes and Their Enhanced Reactivity in σ-Bond Metathesis Processes with Si-H and C-H Bonds
• Authors of publication: Aaron D. Sadow; T. Don Tilley
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 9462 - 9475
• a: 20.1825 ± 0.0002 Å
• b: 21.129 ± 0.0005 Å
• c: 10.016 ± 0.0002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4271.18 ± 0.14 ų
• Cell temperature: 174.2 K
• Ambient diffraction temperature: 174.2 K
• Number of distinct elements: 6
• Space group number: 18
• Hermann-Mauguin space group symbol: P 21 21 2
• Hall space group symbol: P 2 2ab
• Residual factor for all reflections: 0.0886
• Residual factor for significantly intense reflections: 0.035
• Weighted residual factors for all reflections: 0.0441
• Weighted residual factors for significantly intense reflections: 0.032
• Weighted residual factors for all reflections included in the refinement: 0.032
• Goodness-of-fit parameter for all reflections included in the refinement: 0.853
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No