Information card for entry 4115431

Structure parameters

• Formula: C26 H47 N9 O13 Pt2
• Calculated formula: C26 N9 O13 Pt2
• SMILES: [Pt]12([Pt]([NH2]C(=[O]1)C(C)(C)C)([NH2]C(=[O]2)C(C)(C)C)([NH3])[NH3])([NH3])([NH3])CC(=O)c1ccccc1.O=N(=O)[O-].O=N(=O)[O-].O=N(=O)[O-].O=C(C)c1ccccc1
• Title of publication: Synthesis of Ketonylplatinum(III) Dinuclear Complexes: Observation of the Competitive Radical vs Electrophilic Displacement in Pt(III)-Promoted C-H Bond Activation of Ketones
• Authors of publication: Yong-Shou Lin; Hanae Misawa; Jun Yamada; Kazuko Matsumoto
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2001
• Journal volume: 123
• Pages of publication: 569 - 575
• a: 10.133 ± 0.002 Å
• b: 9.684 ± 0.002 Å
• c: 38.1 ± 0.01 Å
• α: 90°
• β: 90.86 ± 0.02°
• γ: 90°
• Cell volume: 3738.3 ± 1.5 ų
• Cell temperature: 298.2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0683
• Weighted residual factors for all reflections included in the refinement: 0.0723
• Goodness-of-fit parameter for all reflections included in the refinement: 1.554
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No