Information card for entry 4116796

Structure parameters

• Formula: C18 H54 Li Mg N3 Si6
• Calculated formula: C18 H54 Li Mg N3 Si6
• SMILES: [Si]([N]1([Si](C)(C)C)[Mg]([N]([Si](C)(C)C)([Si](C)(C)C)[Li]1)N([Si](C)(C)C)[Si](C)(C)C)(C)(C)C
• Title of publication: Intermetallic Lithium-Magnesium Hexamethyldisilazide: Synthesis and Structure, Discovery of an Oxygen-Centered Variant, and a Reaction with Benzonitrile That Produces a Novel Amidinate Cage Compound with a Trigonal Bipyramidal Li4MgO Core
• Authors of publication: Alan R. Kennedy; Robert E. Mulvey; René B. Rowlings
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 1998
• Journal volume: 120
• Pages of publication: 7816 - 7824
• a: 8.994 ± 0.002 Å
• b: 11.44 ± 0.005 Å
• c: 16.62 ± 0.004 Å
• α: 98.33 ± 0.02°
• β: 92.568 ± 0.019°
• γ: 105 ± 0.03°
• Cell volume: 1628.3 ± 0.9 ų
• Cell temperature: 123 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1434
• Residual factor for significantly intense reflections: 0.0581
• Weighted residual factors for significantly intense reflections: 0.1457
• Weighted residual factors for all reflections included in the refinement: 0.1724
• Goodness-of-fit parameter for all reflections included in the refinement: 1.015
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No