Information card for entry 4118769

Structure parameters

• Formula: C23 H26 O Si
• Calculated formula: C23 H26 O Si
• SMILES: [Si@@](c1ccccc1c1c(O)cccc1)(c1ccccc1)(C)C(C)(C)C
• Title of publication: Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation
• Authors of publication: Ryo Shintani; Eleanor E. Maciver; Fumiko Tamakuni; Tamio Hayashi
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2012
• Journal volume: 134
• Pages of publication: 16955 - 16958
• a: 9.68805 ± 0.00018 Å
• b: 10.08629 ± 0.00018 Å
• c: 20.5544 ± 0.0004 Å
• α: 90°
• β: 99.1108 ± 0.0007°
• γ: 90°
• Cell volume: 1983.16 ± 0.06 ų
• Cell temperature: 93.1 K
• Ambient diffraction temperature: 93 ± 1 K
• Number of distinct elements: 4
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for significantly intense reflections: 0.0373
• Weighted residual factors for all reflections included in the refinement: 0.1064
• Goodness-of-fit parameter for all reflections included in the refinement: 1.077
• Diffraction radiation wavelength: 1.54187 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No