Information card for entry 4118822

Structure parameters

• Chemical name: 4-(trimethylsilyl)diazenyl-3-[N,N',N'-tris(trimethylsilyl)]hydrazinyl- 1H-pyrazole n-hexane hemisolvate
• Formula: C24 H61 N6 Si6
• Calculated formula: C24 H61 N6 Si6
• Title of publication: Catalytic Trimerization of Bis-silylated Diazomethane
• Authors of publication: Muhammad Farooq Ibad; Peter Langer; Fabian Reiß; Axel Schulz; Alexander Villinger
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2012
• Journal volume: 134
• Pages of publication: 17757 - 17768
• a: 11.5287 ± 0.0004 Å
• b: 12.7713 ± 0.0004 Å
• c: 13.9033 ± 0.0005 Å
• α: 96.101 ± 0.002°
• β: 108.397 ± 0.002°
• γ: 92.853 ± 0.002°
• Cell volume: 1923.91 ± 0.12 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0758
• Residual factor for significantly intense reflections: 0.0434
• Weighted residual factors for significantly intense reflections: 0.1149
• Weighted residual factors for all reflections included in the refinement: 0.1251
• Goodness-of-fit parameter for all reflections included in the refinement: 1.069
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No