Information card for entry 4121355

Structure parameters

• Formula: C53.5 H82 Cl2 P4 Ru2 Si2
• Calculated formula: C53.5 H82 Cl2 P4 Ru2 Si2
• Title of publication: Reversible Insertion of Carbenes into Ruthenium-Silicon Bonds
• Authors of publication: María J. Bernal; Olga Torres; Marta Martín; Eduardo Sola
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2013
• Journal volume: 135
• Pages of publication: 19008 - 19015
• a: 10.7041 ± 0.0015 Å
• b: 47.995 ± 0.007 Å
• c: 11.3362 ± 0.0016 Å
• α: 90°
• β: 106.13 ± 0.002°
• γ: 90°
• Cell volume: 5594.6 ± 1.4 ų
• Cell temperature: 100 ± 0.2 K
• Ambient diffraction temperature: 100 ± 0.2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0681
• Residual factor for significantly intense reflections: 0.0368
• Weighted residual factors for significantly intense reflections: 0.0596
• Weighted residual factors for all reflections included in the refinement: 0.065
• Goodness-of-fit parameter for all reflections included in the refinement: 0.845
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No