Information card for entry 4123150

Structure parameters

• Formula: C27 H51 P3 Si3 W
• Calculated formula: C27 H51 P3 Si3 W
• SMILES: [WH4]([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)([SiH2][SiH](c1ccccc1)c1ccccc1)[SiH2]c1ccccc1
• Title of publication: σ-Silane, Disilanyl, and [W(μ-H)Si(μ-H)W] Bridging Silylene Complexes via the Reactions of W(PMe3)4(η(2)-CH2PMe2)H with Phenylsilanes.
• Authors of publication: Zuzek, Ashley A.; Neary, Michelle C.; Parkin, Gerard
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Pages of publication: 141217070549000
• a: 9.6573 ± 0.0009 Å
• b: 16.3977 ± 0.0015 Å
• c: 21.2536 ± 0.0019 Å
• α: 90°
• β: 94.398 ± 0.001°
• γ: 90°
• Cell volume: 3355.8 ± 0.5 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1062
• Residual factor for significantly intense reflections: 0.0524
• Weighted residual factors for significantly intense reflections: 0.0943
• Weighted residual factors for all reflections included in the refinement: 0.1119
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No