Information card for entry 4123246

Structure parameters

• Chemical name: Rh(dipope)(h6-BArF4)
• Formula: C48.5 H50 B F24 O4 P2 Rh
• Calculated formula: C48.5 H50 B F24 O4 P2 Rh
• Title of publication: Solid-State Synthesis and Characterization of σ-Alkane Complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = Bidentate Chelating Phosphine).
• Authors of publication: Pike, Sebastian D.; Chadwick, F. Mark; Rees, Nicholas H.; Scott, Mark P.; Weller, Andrew S.; Krämer, Tobias; Macgregor, Stuart A.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2015
• Journal volume: 137
• Journal issue: 2
• Pages of publication: 820 - 833
• a: 12.9279 ± 0.0003 Å
• b: 20.8343 ± 0.0004 Å
• c: 21.8302 ± 0.0005 Å
• α: 88.0127 ± 0.001°
• β: 86.0539 ± 0.001°
• γ: 73.0587 ± 0.001°
• Cell volume: 5610.7 ± 0.2 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1026
• Residual factor for significantly intense reflections: 0.0618
• Weighted residual factors for all reflections: 0.1432
• Weighted residual factors for significantly intense reflections: 0.1255
• Weighted residual factors for all reflections included in the refinement: 0.1432
• Goodness-of-fit parameter for all reflections included in the refinement: 0.9544
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No