Syntheses of (+)-30-epi-, (-)-6-epi-, (±)-6,30-epi-13,14-Didehydroxyisogarcinol and (±)-6,30-epi-Garcimultiflorone A Utilizing Highly Diastereoselective, Lewis Acid-Controlled Cyclizations.
Authors of publication
Boyce, Jonathan H.; Eschenbrenner-Lux, Vincent; Porco, Jr, John A
Journal of publication
Journal of the American Chemical Society
Year of publication
2016
Journal volume
138
Journal issue
44
Pages of publication
14789 - 14797
a
14.1854 ± 0.0002 Å
b
19.4283 ± 0.0003 Å
c
19.7516 ± 0.0003 Å
α
90°
β
102.419 ± 0.001°
γ
90°
Cell volume
5316.13 ± 0.14 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
3
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0437
Residual factor for significantly intense reflections
0.0411
Weighted residual factors for significantly intense reflections
0.1068
Weighted residual factors for all reflections included in the refinement
0.1094
Goodness-of-fit parameter for all reflections included in the refinement
