Information card for entry 4127065

Structure parameters

• Chemical name: [Rh(iPrXant)(H)2(H3BNMe3)][BArF4]
• Formula: C62 H66 B2 F24 N O P2 Rh
• Calculated formula: C62 H66 B2 F24 N O P2 Rh
• Title of publication: Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts.
• Authors of publication: Adams, Gemma M.; Colebatch, Annie L.; Skornia, Joseph T.; McKay, Alasdair I.; Johnson, Heather C.; Lloyd Jones, Guy C.; Macgregor, Stuart A.; Beattie, Nicholas A.; Weller, Andrew S.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• a: 19.3278 ± 0.0001 Å
• b: 13.1158 ± 0.0001 Å
• c: 26.1296 ± 0.0002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6623.84 ± 0.08 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 8
• Space group number: 29
• Hermann-Mauguin space group symbol: P c a 21
• Hall space group symbol: P 2c -2ac
• Residual factor for all reflections: 0.0409
• Residual factor for significantly intense reflections: 0.04
• Weighted residual factors for all reflections: 0.1049
• Weighted residual factors for significantly intense reflections: 0.1039
• Weighted residual factors for all reflections included in the refinement: 0.1048
• Goodness-of-fit parameter for all reflections included in the refinement: 0.9794
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No