Information card for entry 4127554

Structure parameters

• Chemical name: [BP2]Co(SiHPhCH2PiPr2)H2
• Formula: C33 H61 B Co P3 Si
• Calculated formula: C33 H61 B Co P3 Si
• SMILES: [CoH2]12([P](C(C)C)(C(C)C)CB(c3ccccc3)C[P]1(C(C)C)C(C)C)[P](C(C)C)(C(C)C)C[SiH]2c1ccccc1
• Title of publication: Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores.
• Authors of publication: Handford, Rex C.; Smith, Patrick W.; Tilley, T. Don
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2019
• Journal volume: 141
• Journal issue: 22
• Pages of publication: 8769 - 8772
• a: 13.211 ± 0.0006 Å
• b: 19.7623 ± 0.001 Å
• c: 13.6214 ± 0.0007 Å
• α: 90°
• β: 91.36 ± 0.002°
• γ: 90°
• Cell volume: 3555.3 ± 0.3 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.054
• Residual factor for significantly intense reflections: 0.0373
• Weighted residual factors for significantly intense reflections: 0.0775
• Weighted residual factors for all reflections included in the refinement: 0.0842
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.7288 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No