Information card for entry 4128328

Structure parameters

• Formula: C72 H198 Au24 Pt S18 Si18
• Calculated formula: C72 H198 Au24 Pt S18 Si18
• Title of publication: Efficient and Selective Conversion of Phosphine-Protected (MAu₈)²⁺ (M = Pd, Pt) Superatoms to Thiolate-Protected (MAu₁₂)⁶⁺ or Alkynyl-Protected (MAu₁₂)⁴⁺ Superatoms via Hydride Doping.
• Authors of publication: Takano, Shinjiro; Ito, Shun; Tsukuda, Tatsuya
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2019
• Journal volume: 141
• Journal issue: 40
• Pages of publication: 15994 - 16002
• a: 16.883 ± 0.003 Å
• b: 16.927 ± 0.003 Å
• c: 17.005 ± 0.003 Å
• α: 103.829 ± 0.001°
• β: 112.014 ± 0.001°
• γ: 107.241 ± 0.001°
• Cell volume: 3952.2 ± 1.2 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.044
• Residual factor for significantly intense reflections: 0.0355
• Weighted residual factors for significantly intense reflections: 0.0604
• Weighted residual factors for all reflections included in the refinement: 0.0638
• Goodness-of-fit parameter for all reflections included in the refinement: 0.971
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No