Information card for entry 4128333

Structure parameters

• Formula: C72 H198 Au24 Pd S18 Si18
• Calculated formula: C72 H198 Au24 Pd S18 Si18
• Title of publication: Efficient and Selective Conversion of Phosphine-Protected (MAu₈)²⁺ (M = Pd, Pt) Superatoms to Thiolate-Protected (MAu₁₂)⁶⁺ or Alkynyl-Protected (MAu₁₂)⁴⁺ Superatoms via Hydride Doping.
• Authors of publication: Takano, Shinjiro; Ito, Shun; Tsukuda, Tatsuya
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2019
• Journal volume: 141
• Journal issue: 40
• Pages of publication: 15994 - 16002
• a: 16.8731 ± 0.0004 Å
• b: 16.9117 ± 0.0004 Å
• c: 17.0006 ± 0.0004 Å
• α: 103.768 ± 0.002°
• β: 112.008 ± 0.002°
• γ: 107.269 ± 0.002°
• Cell volume: 3946.7 ± 0.2 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0403
• Residual factor for significantly intense reflections: 0.0354
• Weighted residual factors for significantly intense reflections: 0.1046
• Weighted residual factors for all reflections included in the refinement: 0.1067
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No