Information card for entry 4128487

Structure parameters

• Formula: C37 H68 N5 Ni P Si2
• Calculated formula: C37 H68 N5 Ni P Si2
• Title of publication: Versatile Tautomerization of EH₂-Substituted Silylenes (E = N, P, As) in the Coordination Sphere of Nickel.
• Authors of publication: Hadlington, Terrance J.; Szilvási, Tibor; Driess, Matthias
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2019
• Journal volume: 141
• Journal issue: 7
• Pages of publication: 3304 - 3314
• a: 18.5935 ± 0.0003 Å
• b: 18.54 ± 0.0003 Å
• c: 24.548 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8462.3 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0559
• Residual factor for significantly intense reflections: 0.0381
• Weighted residual factors for significantly intense reflections: 0.0945
• Weighted residual factors for all reflections included in the refinement: 0.1053
• Goodness-of-fit parameter for all reflections included in the refinement: 1.015
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No