Information card for entry 4128492

Structure parameters

• Formula: C46 H90 As Li N7 Ni Si2
• Calculated formula: C46 H90 As Li N7 Ni Si2
• Title of publication: Versatile Tautomerization of EH₂-Substituted Silylenes (E = N, P, As) in the Coordination Sphere of Nickel.
• Authors of publication: Hadlington, Terrance J.; Szilvási, Tibor; Driess, Matthias
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2019
• Journal volume: 141
• Journal issue: 7
• Pages of publication: 3304 - 3314
• a: 15.7427 ± 0.0004 Å
• b: 18.018 ± 0.0006 Å
• c: 20.4069 ± 0.0006 Å
• α: 91.496 ± 0.003°
• β: 102.225 ± 0.002°
• γ: 103.698 ± 0.003°
• Cell volume: 5478.5 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0648
• Residual factor for significantly intense reflections: 0.0434
• Weighted residual factors for significantly intense reflections: 0.1056
• Weighted residual factors for all reflections included in the refinement: 0.1194
• Goodness-of-fit parameter for all reflections included in the refinement: 1.013
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No